is defined as the mass of the , which in your case is ##”HCl”##, divided by the total mass of the solution and multiplied by 100.
The easiest way to approach such solution problems is by picking a convenient sample of the solution to base the calculations on. In this case, let’s pick a ##”1-L”## sample of your ##”38%## concentration by mass solution.
The first thing you need to do is determine is how much the ##”1-L”## sample weighs. Since was given to you ##”g/cm”^3##, it’ll be best to transform it in ##”g/dm”^3##, since ##”1 L = 1 dm”^3##
##1.19 “g”/”cm”^3 * (“1000 cm”^3)/(“1 dm”^3) = “1190 g/dm”^3##
Now focus on finding out how much ##”HCl”## you have in this much solution.
##”38%” = m_(“[solute](http://socratic.org/chemistry/solutions-and-their-behavior/solute)”)/m_(“solution”) * 100 => m_(“solute”) = (m_(“solution”) * 38)/100##
##m_(“solute”) = (38 * 1190)/100 = “452.2 g HCl”##
For , you need moles of solute per liter of solution. Use ##”HCl”##’s molar mass to determine how many moles you have
##”452.2 g” * (“1 mole”)/(“36.5 g”) = “12.40 moles HCl”##
Therefore,
##C = n/V = “12.40 moles”/”1 L” = “12.4 M”##
will be moles of solute per kilogram of solution, so
##”b” = n_(“solute”)/m_(“solution”) = (“12.40 moles”)/(1190 * 10^(-3)”kg”) = “10.4 molal”##
For mole fraction you first need to determine the total number of moles you have in the sample. Find the number of moles of water by
##m_(“water”) = “1190 g” – “452.2 g” = “737.8 g”##
##”737.8 g” * (“1 mole”)/(“18.0 g”) = “41.0 moles water”##
The total number of moles will be
##n_(“total”) = n_(“water”) + n_(“solute”) = 41.0 + 12.40 = “53.4 moles”##
Therefore, fraction for ##”HCl”## is
##”mole fraction” = n_(“solute”)/n_(“total”) = 0.232##
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